Cyclohexanone - Alchetron, The Free Social Encyclopedia
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Cyclohexanone - Alchetron, The Free Social Encyclopedia
Cyclohexanone is the organic compound with the formula (CH2)5CO. The molecule consists of sixcarbon cyclic molecule with a ketone functional group. This colorless oil has an odor reminiscent of peardrop sweets as well as acetone. Over time, samples assume a yellow color due to oxidation. Cyclohexan
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23-64 The Stork enamine reaction and the intramolecular aldol reaction canbe carried out in sequence to allow the synthesis of cyclohexenones.For example, reaction of the pyrrolidine enamine of cyclohexanonewith 3-buten-2-one, followed by enamine hydrolysis and base treat-ment, yields the product indicated. Write each step, and show themechanism of each.
23-64 The Stork enamine reaction and the intramolecular aldol reaction canbe carried out in sequence to allow the synthesis of cyclohexenones.For example, reaction of the pyrrolidine enamine of cyclohexanonewith 3-buten-2-one, followed by enamine hydrolysis and base treat-ment, yields the product indicated. Write each step, and show themechanism of each.
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SOLVED:Propose a synthesis of beginning with cyclohexanone, and 3 -bromopropanol. [Hint: Beware of a possible pitfall in planning this synthesis (recall Section 8-9).]
SOLVED:Propose a synthesis of beginning with cyclohexanone, and 3 -bromopropanol. [Hint: Beware of a possible pitfall in planning this synthesis (recall Section 8-9).]
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